Asahi Kasei Receives Imperial Invention Prize in Japan for Nickel-Coated Absorption Layer - Mitigating the Deterioration of Electrodes and Contributing to a Stable, Long-Term Electrolyzer Operation
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Ion-exchange membrane process for chlor-alkali electrolysis
Chlor-alkali electrolysis uses ion-exchange membranes to produce chlorine, caustic soda, and hydrogen through the electrolysis of brine. Since its commercialization by Asahi Kasei in 1975, this process has been adopted at over 160 plants in more than 30 countries worldwide (as of
The awarded nickel-coated absorption layer addresses a long-term key issue of the chlor-alkali electrolysis process: When the electrolysis is stopped due to temporary reductions in demand for chlorine and caustic soda, equipment malfunctions, or power outages, the electrodes—especially the cathode—deteriorate due to reverse current. This leads to problems such as increased power consumption and shortened cathode service life. Conventional measures have used mechanical solutions to suppress such reverse current. However, this approach is susceptible to malfunctions and operator errors, making it challenging to avoid cathode deterioration completely.
Installing a reverse current absorption layer with a nickel coating offers an alternative method to eliminate the need for mechanical equipment. When stopping the electrolysis process, the reverse current absorption layer undergoes a chemical reaction with the nickel, preventing cathode degradation and enabling the equipment's stable, long-term operation.
The nickel-coated reverse current absorption layer overcomes an additional hurdle for electrolyzer operators. Previously, customers often had to compromise porosity for strength and vice versa. Asahi Kasei’s technology remedies this issue with its nickel-coated layer, which is both porous and sturdy while remaining processable over large areas. Commercialization was successfully achieved by applying nickel to a substrate with thermal spraying, which involves heating a material to a molten or near-molten state and applying it onto a surface to form a coating.
Akiyasu Funakawa, General Manager of Asahi Kasei’s
Chlor-alkali electrolysis equipment incorporating this technical breakthrough has already been adopted by chemical manufacturers worldwide, with market expansion continuing. Asahi Kasei is also investigating the technology’s applicability to other electrolysis processes, such as alkaline water electrolysis for green hydrogen production.
In addition to the Imperial Invention Prize,
For additional information on Asahi Kasei’s Ion-Exchange Membrane Business, visit https://chlor-alkali.asahi-kasei.co.jp/en/
The Imperial Invention Prize
Akiyasu Funakawa
General Manager
Ion Exchange Membrane & Electrolysis System Division
General Manager
Microza & Water Processing Division
Award for Distinguished Contribution for Driving the Invention into Implementation
President and Representative Director
(Affiliations are current as of the date of the award.)
About Asahi Kasei
Asahi Kasei is also dedicated to sustainability initiatives and is contributing to reaching a carbon neutral society by 2050. To learn more, visit https://www.asahi-kasei.com/sustainability/.
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North America Contact:
christian.okeefe@ak-america.com
Europe Contact:
sebastian.schmidt@asahi-kasei.eu
Source: Asahi Kasei